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Creators/Authors contains: "Beach, Stephanie A."

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  1. ; ; ; ; ; ; ; ; ; (, Chemical Communications)
    null (Ed.)
    The new PtVO(SOCR) 4 lantern complexes, 1 (R = CH 3 ) and 2 (R = Ph) behave as neutral O-donor ligands to Ln(OR) 3 with Ln = Ce, Nd. Four heterotrimetallic complexes with linear {LnOVPt} units were prepared: [Ln(ODtbp) 3 {PtVO(SOCR) 4 }] (Ln = Ce, 3Ce (R = CH 3 ), 4Ce (R = Ph); Nd, 3Nd (R = CH 3 ), 4Nd (R = Ph); ODtbp = 2,6-ditertbutylphenolate). Magnetic characterization confirms slow magnetic relaxation behaviour and suggests antiferromagnetic coupling across {Ln–OV} in all four complexes, with variations tunable as a function of Ln and R. 
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  2. ; ; ; ; ; (, Inorganica Chimica Acta)
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